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CO2 Capture Through Ocean Water Mineralization

Writer's picture: ENV Tech BlogENV Tech Blog

Updated: Jan 7, 2024

Transforming carbon dioxide in the ocean into useful resources


Introduction

The Saline Water-Based Mineralization Pathway (SWMP) for large-scale CO2 Management might just change the Direct Carbon Capture (DCC) field. Scientists predict that this technology, if implemented succesfully, can play a landmark role in CO2 capture in the future. Let's embark on a scientific adventure to explore this groundbreaking technology that promises to change the trajectory of our planet's future.



The Ingenious SWMP Process:


SWMP is a novel approach that harnesses the power of saline water to capture and convert CO2 emissions into valuable solid carbonate minerals. It's like nature's very own recycling program for greenhouse gases!


Image by Erika Callagon La Plante Via [https://pubs.acs.org/doi/full/10.1021/acssuschemeng.0c08561 Copyright-free


Step 1: Carbon Dioxide Capture

Saline water, like the salty seas that stretch across our planet, plays an essential role in this transformative process. When CO2 interacts with saline water, a fascinating series of chemical reactions, or what some might even call alchemy, occurs. The CO2 dissolves into the water, forming stable bicarbonates, which are just compounds with HCO3- in them. This is a big change from the gaseous form of CO2. This chemical change marks the first crucial step in the SWMP process.


CO2 (g) + H2O (aq) ⇌ H2CO3 (aq) ⇌ HCO3- (aq) + H+ (aq)


Fun fact: Baking soda, or sodium bicarbonate is a type of bicarbonate.


Photo (above): Baking Soda, Sodium Bicarbonate, or NaHCO3


Step 2: Mineralization Magic

Now, brace yourself for the true marvel of SWMP! The bicarbonates formed in Step 1 embark on an enchanting journey when introduced to alkaline-rich materials like olivine or serpentine, both very common minerals. Like skilled alchemists, these materials catalyze a reaction that converts the bicarbonates into solid carbonate minerals. It's like a power ranger transformation: CO2 molecules convert into a stronger and more "useful" substance. They minerals formed could include magnesium carbonate, but depend on which mineral is used.


Ex. 2HCO3- (aq) + Mg2SiO4 (s) → 2CO32- (s) + Mg2+ (aq) + H2SiO4 (aq)


Step 3: Reaping the carbonate

The final act of SWMP brings forth a bounty of carbonate minerals. These stable carbonates serve a dual purpose—removing CO2 from the ocean while feeding into applications of various industries. From revolutionizing concrete construction to offering an eco-friendly alternative in resource utilization, the solid carbonates stand as testaments to the ingenuity of sustainable engineering.



SWMP: A Comparison


Now, you might wonder how SWMP compares to traditional CO2 management approaches. Imagine conventional methods as mere Band-Aids on a wound—a temporary fix that doesn't address the root cause. For example, direct carbon capture must store its carbon dioxide in gas tanks. Not only is the process extremely inefficient, it also wastes CO2, which has many applications. SWMP, on the other hand, acts as a transformative remedy that heals and regenerates.


1. Cost-Effectiveness: SWMP's utilization of abundant saline water and natural mineralization processes holds the promise of being a more cost-effective alternative to conventional carbon capture and storage methods.


2. Versatility: Beyond CO2 management, SWMP demonstrates applications in air purification, hydrogen gas production, and organic pollutant degradation, showcasing its potential in addressing a range of environmental challenges.


3. Resource Efficiency: SWMP's focus on saline water as a resource and the utilization of solid carbonate minerals in construction and industrial processes contribute to resource efficiency and sustainability.



Challenges and Ongoing Research Efforts:


As with any innovative technology, SWMP faces several challenges that require ongoing research and development:


1. Reaction Efficiency: The efficiency of mineralization processes and the time required for CO2 transformation remain subjects of ongoing research. Optimizing reaction rates and enhancing efficiency is essential to maximize the impact of SWMP.


2. Scalability: Scaling up SWMP for gigatonne-scale CO2 management demands further research and development to ensure practical feasibility and large-scale applicability.


3. Energy Requirements: SWMP may require energy inputs during CO2 capture and mineralization processes. Minimizing energy consumption is vital to enhance SWMP's sustainability.


4. Environmental protection: By removing CO2 from the ocean, there are a few possible dangers, especially to marine life. It could change pH levels and CO2 availability, leading to an imbalance of a few marine ecosystems.



Conclusion:


In summary, the Saline Water-Based Mineralization Pathway (SWMP) is a game-changer for handling CO2 emissions by using salty water to create useful minerals. SWMP is efficient, versatile, and cost-effective, offering potential applications beyond just managing CO2. Although there are challenges like improving efficiency and scaling up the process, ongoing research aims to make SWMP even better. This simple yet innovative technology not only tackles CO2 emissions but also contributes to sustainability and a greener future.



Author's Note:


The journey of SWMP fills me with excitement and optimism. Just as the saline seas encompass our planet, SWMP embraces us in its quest to combat climate change. As we explore the boundless potential of SWMP, may we be inspired to take bold steps towards a world where environmental challenges are met with creative and sustainable solutions. Together, we hold the power to steer our planet towards a brighter, more resilient tomorrow.



Works Cited

Gabrielli, P., Gazzani, M., & Mazzotti, M. (2020). The role of carbon capture and utilization, carbon capture and storage, and biomass to enable a net-zero-CO2 emissions chemical industry. Industrial & Engineering Chemistry Research, 59(15), 7033–7045. https://doi.org/10.1021/acs.iecr.9b06579

La Plante, E. C., Simonetti, D. A., Wang, J., Al-Turki, A., Chen, X., Jassby, D., & Sant, G. N. (2021). Saline water-based mineralization pathway for gigatonne-scale CO2 management. ACS Sustainable Chemistry & Engineering, 9(3), 1073–1089. https://doi.org/10.1021/acssuschemeng.0c08561



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The ENV Tech Blog strives to increase the transparency of real, meaningful research between the scientific community and the people. We focus on the pressing problem of climate change and environmental technology solutions in this blog. Through writing and simplifying the latest and (cool) research in this field, we hope to educate and engage more people in creating solutions for climate change problems. Thanks so much for stopping by!

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